The Ghana international peeled away from his marker to comfortably direct a low cross from Patrick van Aanholt to double their lead in the 23rd minute.
Luka Milivojevic had given the Eagles the go-ahead goal on 12 minutes with a sumptuous free-kick from the edge of the box.
Ayew has now scored 26 goals in the English top-flight since signing for Aston Villa five years ago.
The 28-year-old is now two away from equalling his personal best of 12 goals during his spell with French Ligue 1 side Lorient for the 2014/15 season.
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